Abstract

HABCHI, M.; MESLI, S. M.; ZIANE, M.  and  KOTBI, M.. Solvation structure of the Chloride Lithium-ion pair at the supercooled state from Hybrid Reverse Monte Carlo simulation combined to neutron scattering. Rev. mex. fis. [online]. 2020, vol.66, n.3, pp.258-264.  Epub Mar 26, 2021. ISSN 0035-001X.  https://doi.org/10.31349/revmexfis.66.258.

A detailed analysis of the hydration shells of the 9.26 molal LiCl aqueous solution at the intermediate metastable thermodynamic state between the liquid (300 k) and the glass (120 k). The structural modeling of the LiCl6H2O at the supercooled-liquid state is conducted employing the Hybrid Reverse Monte Carlo simulation, in combination with the neutron scattering data. The obtained pair distribution functions and the running coordination number are used as interpretive tools to examine the repartition of the water molecules around ions of lithium and chloride. HRMC represents a powerful tool to provide detailed information on the hydration shell structures through the obtained pair correlations.

Keywords : Partial and pair distribution functions; HRMC simulation; glassy; supercooled-liquid and liquid state; 61.20.Ja; 82.45.Gj; 12.39.Pn.