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Revista mexicana de física
versión impresa ISSN 0035-001X
Resumen
CHAVEZ RIVAS, F.; PETRANOVSKII, V y ZAMORANO ULLOA, R.. Crecimiento de nanopartículas de cobre en matriz de erionita. Rev. mex. fis. [online]. 2010, vol.56, n.4, pp.328-333. ISSN 0035-001X.
Unreduced and reduced in hydrogen flow copper exchanged synthetic erionite, with a SiO2/Al2O3 molar ratio of 7.7, have been characterized by X-ray diffraction (XRD), UV-Vis diffuse reflectance spectroscopy (DRS), and electron spin resonance spectroscopy (ESR). The XRD patterns show that the reduction process does not change the zeolite structure, besides the reduced form at 450° C present diffraction lines assigned to copper metallic particles. The DRS measurements have detected isolated Cu2+ ions as well as plasma resonance peak of copper metallic nanoparticles. The ESR simulation analysis of the spectra measured at 20°C indicates the presence of two different Cu2+ ions sites localized in the erionite matrix. Up to 450° C only one type of sites take place in the reduction process, participating in Cu metal clusters and Cu metal nanoparticles formation, keeping the Cu2+ ions of the second site intact.
Palabras llave : Erionite; copper nanoparticles; ESR; UV-Vis.