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Journal of the Mexican Chemical Society
versión impresa ISSN 1870-249X
Resumen
MALEKI, Behrooz; TAYEBEE, Reza; KERMANIAN, Mina y SEDIGH ASHRAFI, Samaneh. One-Pot Synthesis of 1,8-Dioxodecahydroacridines and Polyhydroquinoline using 1,3-Di (bromo or chloro)-5,5-Dimethylhydantoin as a Novel and Green Catalyst under Solvent-Free Conditions. J. Mex. Chem. Soc [online]. 2013, vol.57, n.4, pp.290-297. ISSN 1870-249X.
Abstract Solvent-free, one-pot synthesis of polyhdroquinoline and 1,8-dioxodecahydroacridine derivatives have been described via Hantzsch condensation of various aldehydes, ammonium acetate with (i) cyclic 1,3-dicarbonyl compounds and ethyl acetoacetate and (ii) cyclic 1,3-dicarbonyl compounds (2 mmoles) in a very simple, efficient, and environmentally benign method using 1,3-(dibromo or dichloro)-5,5-dimethylhydantoin as a cheap, non-toxic and neutral catalyst with up to excellent yields.
Palabras llave : Aldehydes; cyclic 1,3-dicarbonyl compounds; ammonium acetate; ethyl acetoacetate; green catalyst; solvent-free conditions; one-pot synthesis.