Resumo

ALVAREZ-AMPARAN, M.A.  e  CEDENO-CAERO, L.. Oxidative desulfurization of dibenzothiophenes using VO_x/ZrO₂-Al₂O₃. Rev. Mex. Ing. Quím [online]. 2012, vol.11, n.3, pp.431-438. ISSN 1665-2738.

Vanadium oxide catalysts were nrepared by incipient wetness impregnation of ammonium metavanadate on a zirconia-alumina mixed oxide with different vanadium loading (8, 10 and 15 wt.% of V), in order to increase the performance in oxidative desulfurization (ODS) of dibenzothiophene compounds, using H₂O₂ or tert-butyl hydroperoxide as oxidant. In addition, the catalyst with 15% of V was modified creating vanadium oxides partially reduced. The oxidation states and reducibility of vanadium catalysts were studied by temperature-pcogzammed reduztion (TPR). The cataSysts were characterized by scanning electron microscopy (SEM-EDX) and X-ray diffraction (XRD). Catalytic performance was discussed in terms of vanadium species prevailing on the catalysts, which increase the reactivity of refractory HDS compounds present in diesel fuel (DBT, 4-MDBT, and 4,6-DMDBT).

Palavras-chave : oxidative desulfurization; ZrO₂-Al₂O₃; vanadium oxide; dibenzothiophenes.