Resumo

MEZA-GALVEZ, J. et al. Amorphous Zr(OH)₄ to t-ZrO₂ transformed isothermally. Superf. vacío [online]. 2018, vol.31, n.3, pp.44-47. ISSN 1665-3521.

With the aim to study the transformation from the commercially amorphous Zr(OH)4 to the t-ZrO2, phase, the starting material was isothermally treated in a calorimeter at 350, 365, 370, 375 and 380 o C. The TGA coupled to the DSC technique was used to determine with high precision both the temperature and time necessary to achieve the amorphous Zr(OH)4 to t-ZrO2 transformation. The mass loss and heat flow, as a function of time, were monitored to study the dehydroxylation of Zr(OH)4 and the crystallization processes, respectively. Raman spectroscopy was used to obtain evidence of the t-ZrO2 formation. The DSC results show an exothermic peak (typical of amorphous-crystalline transitions) related to the formation of t-ZrO2. Our results indicate that the time necessary to obtain the t-ZrO2 phase shortens when temperature increases.

Palavras-chave : Zirconium hydroxide; Tetragonal Zirconia; Isothermal treatment; Raman spectroscopy.