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Journal of the Mexican Chemical Society
versão impressa ISSN 1870-249X
Resumo
MONTALVO, Liliana; BOLANOS, Alberto e CABRERA, Armando. Catalytic Activity of Rhodium (I) Complexes with Bidentate Phosphinic Ligands in the Hydrogenation of Unsaturated Alycyclic Substrates. J. Mex. Chem. Soc [online]. 2007, vol.51, n.1, pp.08-14. ISSN 1870-249X.
RhCl(dppe)2, RhCl(dppp)2 and RhCl(dppb)2 where dppe = diphenylphosphinoethane; dppp = diphenylphosphinopropane; dppb = diphenylphosphinobutane complexes were prepared by treating RhCl3.3H2O with the appropriate di(tertiaryphosphine). These complexes were used as catalytic precursors in the hydrogenation of limonene, camphene and 1,5- cyclooctadiene at different concentrations and temperatures. It was found that the Rhodium complex having dppp as ligand was the best catalytic precursor.
Palavras-chave : Rhodium; bidentate phosphinic ligands; homogeneous catalysis; catalytic hydrogenation; unsaturated alycyclic compounds.